W-042.04.031 [2021-03] Negative p Value, Negative m Value in Boiler Water (Alkaline Capacity up to pH 8.2 or 4.3)

Application/Purpose

This method describes how to determine the negative p and m values of boiler water. The concentration of mineral acids (negative m value) is particularly significant in cases when these acids have been released into the boiler feed water through treatment using a strongly acidic cation exchanger.

Scope of Application

Boiler water for use in the production of beer and other foods

Principle

Analogous to the p and m values obtained in the determination of acid capacity (pH 8.2 and 4.3), this analysis is performed according to W-000.13.031 Acid Consumption (Alkalinity, p-Value and m-Value)/Acid Capacity to pH of 8.2 and/or 4.3 for Water. The alkaline capacity of the boiler water is determined through titration of the sample with 0.1 N sodium hydroxide (instead of hydrochloric acid) to a pH of 4.3 and/or 8.2.

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